K-MM radiative Auger (RA) spectra have been measured for several compo
unds containing K and Ca. Transition energies are evaluated by the use
of various sources: the DV-X(alpha) calculation, term values from opt
ical spectroscopy, and L-MM Auger energies. It is shown that the DV-X(
alpha) calculation is very useful in the understanding of RA spectra;
calculated transition energies agree well with observed ones as well a
s those estimated from optical data, giving an unambiguous assignment
for the observed spectra. On the other hand, transition energies evalu
ated from L-MM Auger energies sometimes disagree with others. Possible
reasons for the discrepancy are discussed.