TEMPLATE-INDUCED CONTROL OF STEREOCHEMISTRY FOR THE SYNTHESIS OF LINEAR VINYL-POLYMERS

Authors
WULFF G GLADOW S KUHNEWEG B KRIEGER S
Citation
G. Wulff et al., TEMPLATE-INDUCED CONTROL OF STEREOCHEMISTRY FOR THE SYNTHESIS OF LINEAR VINYL-POLYMERS, Macromolecular symposia, 101, 1996, pp. 355-362
Citations number
22
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular symposia → ACNP
ISSN journal
10221360
Volume
101
Year of publication
1996
Pages
355 - 362
Database
ISI
SICI code
1022-1360(1996)101:<355:TCOSFT>2.0.ZU;2-4
Abstract
Asymmetric cyclocopolymerization of judiciously designed bifunctional monomers with a number of common comonomers affords optically active v inyl polymers with main chain chirality. Tacticity and sequence of com onomeric units can be controlled and thus complicated structures built up. Under different reaction conditions the same bifunctional monomer 1 can undergo cyclization involving a 19-, a 21-, or an 18-membered r ing. With monomer 3 an 11-membered ring is formed.