BASE-MEDIATED RING-OPENING REACTIONS OF EPISULFONES TO GIVE ALKENYLSULFINATES - A STEREOSELECTIVE SYNTHESIS OF ALKENYL SULFONES

Authors
DISHINGTON AP MUCCIOLI AB SIMPKINS NS
Citation
Ap. Dishington et al., BASE-MEDIATED RING-OPENING REACTIONS OF EPISULFONES TO GIVE ALKENYLSULFINATES - A STEREOSELECTIVE SYNTHESIS OF ALKENYL SULFONES, Synlett, (1), 1996, pp. 27
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):1<27:BRROET>2.0.ZU;2-W
Abstract
A range of episulfones undergo ring-opening to give alkenylsulfinates on treatment with LDA in THF. The sulfinates can then be alkylated wit h a number of alkyl halides to give alkenyl sulfone products in a ster eoselective fashion.