A BIOGENETIC APPROACH TO HALICHOLACTONES - ANOMALOUS CYCLIZATION OF AN EPOXYTRIDECADIENOIC ACID

Authors
WHITE JD JENSEN MS
Citation
Jd. White et Ms. Jensen, A BIOGENETIC APPROACH TO HALICHOLACTONES - ANOMALOUS CYCLIZATION OF AN EPOXYTRIDECADIENOIC ACID, Synlett, (1), 1996, pp. 31
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):1<31:ABATH->2.0.ZU;2-P
Abstract
(11R,12R)-(5Z,8E)- and -(5Z,8Z)-11,12-Epoxy-13-hydroxy-5,8-tridecadien oic acids were synthesized from 3-butyn-1-ol and were shown to cyclize to the delta-lactone of (12S)-(7E, 10E)-5,12,13-trihydroxy-7,10-tride cadienoic acid with stannic chloride in nitromethane.