CONJUGATE ADDITION-ELIMINATION REACTIONS AS A NOVEL SYNTHETIC ROUTE TO DIALKYLATED ALPHA,BETA-UNSATURATED DIESTERS

Authors
DONOFRIO F PARLANTI L PIANCATELLI G
Citation
F. Donofrio et al., CONJUGATE ADDITION-ELIMINATION REACTIONS AS A NOVEL SYNTHETIC ROUTE TO DIALKYLATED ALPHA,BETA-UNSATURATED DIESTERS, Synlett, (1), 1996, pp. 63
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):1<63:CARAAN>2.0.ZU;2-R
Abstract
The paper describes a novel synthetic route for mono- and dialkylation of dimethyl 2-phenylseleno fumarate 1. The conjugate additions to 1 p roceed regio- and stereoselectively. The subsequent oxidative eliminat ions of phenylseleno group provide a convenient procedure for the synt hesis of the title compounds.