THE VIBRATIONAL-SPECTRA OF THE LAYERED COMPOUNDS KSB(PO4)(2) AND CSM(PO4)(2) (M=SB, TA, NB) - NORMAL-COORDINATE ANALYSIS OF KSB(PO4)(2)

Authors
HUSSON E REPELIN Y PIFFARD Y VERBAERE A
Citation
E. Husson et al., THE VIBRATIONAL-SPECTRA OF THE LAYERED COMPOUNDS KSB(PO4)(2) AND CSM(PO4)(2) (M=SB, TA, NB) - NORMAL-COORDINATE ANALYSIS OF KSB(PO4)(2), European journal of solid state and inorganic chemistry, 32(11), 1995, pp. 1077-1088
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
32
Issue
11
Year of publication
1995
Pages
1077 - 1088
Database
ISI
SICI code
0992-4361(1995)32:11<1077:TVOTLC>2.0.ZU;2-6
Abstract
Infrared and Raman spectra on powder samples of KSb(PO4)(2), CsSb(PO4) (2), CsTa(PO4)(2) and CsNb(PO4)(2) and polarized Raman spectra on a si ngle crystal of KSb(PO4)(2) were recorded. A normal coordinate analysi s using a generalized force field was performed for KSb(PO4)(2). The w hole results allowed an assignment of the observed frequencies. It was possible to characterize the P-O, Sb-O and M-O bonds (M = alkaline ca tion) in layered phosphatoantimonates. The strength of the Sb-O, Ta-O and Nb-O bonds is compared.