SYNTHESIS AND STRUCTURE OF 2-IMINO-1,3-DI METHYLIMIDAZOLINE

Authors
KUHN N FAWZI R STEIMANN M WIETHOFF J BLASER D BOESE R
Citation
N. Kuhn et al., SYNTHESIS AND STRUCTURE OF 2-IMINO-1,3-DI METHYLIMIDAZOLINE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(12), 1995, pp. 1779-1784
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
12
Year of publication
1995
Pages
1779 - 1784
Database
ISI
SICI code
0932-0776(1995)50:12<1779:SASO2M>2.0.ZU;2-N
Abstract
Deprotonation of the 2-amino-1,3-dimethylimidazolium salt 5 (obtained through methylation of 2-amino-1-methylimidazole (4)) by KH gives 2-im ino-1,3-dimethylimidazoline 6. The trimethylsilylimino compound 14 is formed on the reaction of 6 with chlorotrimethylsilane in the ratio 2: 1. Further reaction with chlorotrimethylsilane gives the silylated ami noimidazolium salt 15. The X-ray structures of 5 and 6 are reported.