THE SOLVATOCHROMISM OF C-60 AND ITS COLOR IN SOLUTION

Authors
Citation
J. Catalan, THE SOLVATOCHROMISM OF C-60 AND ITS COLOR IN SOLUTION, New journal of chemistry, 19(12), 1995, pp. 1233-1242
Citations number
36
Categorie Soggetti
Chemistry
Journal title
ISSN journal
11440546
Volume
19
Issue
12
Year of publication
1995
Pages
1233 - 1242
Database
ISI
SICI code
1144-0546(1995)19:12<1233:TSOCAI>2.0.ZU;2-S
Abstract
This paper analyses the solvatochromism of C-60 in a wide range of ali phatic and aromatic solvents (nearly 50), as well as in the gas phase, on the basis of the spectral shift induced by the environment on thre e peaks in the UV/vis absorption spectrum of C-60 that are representat ive of the whole spectrum. Solvents are categorized by their solvent d ipolarity-polarizability (SPP) values. In order to analyze the potenti al involvement of C-60 in the formation of charge-transfer or hydrogen -bonding complexes, we studied its behavior in 11 monosubstituted benz ene solvents and as many alkanols.