Lrf. Carvalho et al., MONITORING OF THE ULTRASONIC IRRADIATION EFFECT ON THE EXTRACTION OF AIRBORNE PARTICULATE MATTER BY ION CHROMATOGRAPHY, Analytica chimica acta, 317(1-3), 1995, pp. 171-179
The action of ultrasonic waves in liquids can induce or accelerate che
mical reactions of the liquids and/or substances dissolved. A study on
ultrasonic irradiation effects in aqueous and acetone extracts from a
irborne particulate matter, was developed. Several systems such as sol
vents, filters, standard reference material of airborne particles and
real samples from atmospheric particulate matter were evaluated. The g
eneration of anionic species during the sonication process was confirm
ed by ion chromatography. The change of quantitative and qualitative d
ata has shown that ultrasonic extraction leads to false interpretation
of analytical results.