G. Lins et W. Hartmann, METAL VAPOR DENSITIES IN PSEUDOSPARK SWITCHES WITH TANTALUM CARBIDE CATHODES, Journal of physics. D, Applied physics, 26(12), 1993, pp. 2154-2158
In order to combine high electron emission with low electrode erosion,
the electrodes of high-current pseudospark switches should be made of
materials with low work function and high melting point, such as the
carbides of certain metals. An experimental pseudospark switch was suc
cessively fitted with cathodes of pure molybdenum and molybdenum with
additions of 10 and 30 per cent of tantalum carbide, respectively. The
number densities of molybdenum and tantalum vapours were measured by
laser-induced fluorescence, immediately after the switch had been subj
ected to current pulses of 12 kA in amplitude and 1600 ns duration. Fo
r a pure molybdenum cathode the maximum molybdenum vapour concentratio
n amounted to about 10(18) m-3. It did not change substantially when 1
0% of TaC were added to the cathode material, but it increased by a fa
ctor of two when the TaC content was raised to 30%. The number density
of tantalum vapour was twice as high for 10% of TaC in the electrode
material as for 30%. It is concluded that electron emission occurs pre
ferably in the high-melting TaC regions. With an increase in the conce
ntration of TaC in the bulk material the total current is distributed
over a greater number of emission sites such that the thermal load on
an individual emitter decreases and less material is evaporated. The t
otal number density of Ta including all sublevels of the a4F ground st
ate was about an order of magnitude lower than the Mo vapour concentra
tion. A simple estimate based on the comparison of the vapour pressure
s of Mo and Ta yields a surface temperature in the range from 5000 to
8000 K.