GaN thin films were grown by molecular beam epitaxy on sapphire substr
ates. Scanning electron (SE) and atomic force microscopies reveal that
on a typical film an assembly of oriented hexagonal microcrystallites
rises above a background of polycrystalline or amorphous material. Ca
thodoluminescence (CL) spectra of the films feature bright UV exciton
peaks and a broad green emission band. We identify the exciton peaks a
s those of the wurtzite form of GaN. A comparison of SE and CL microgr
aphs of the same sample area shows that the luminescence emanates almo
st entirely from the hexagonal crystallites. (C) 1996 American Institu
te of Physics.