DETERMINATION OF THE EXCITED-STATE DIPOLE-MOMENT OF FLUORENONE USING THE METHOD OF SOLVATOCHROMISM

Citation
Sa. Rani et al., DETERMINATION OF THE EXCITED-STATE DIPOLE-MOMENT OF FLUORENONE USING THE METHOD OF SOLVATOCHROMISM, SPECT ACT A, 51(14), 1995, pp. 2473-2479
Citations number
26
Categorie Soggetti
Spectroscopy
ISSN journal
13861425
Volume
51
Issue
14
Year of publication
1995
Pages
2473 - 2479
Database
ISI
SICI code
1386-1425(1995)51:14<2473:DOTEDO>2.0.ZU;2-W
Abstract
The absorption spectra and steady state fluorescence spectra of fluore none have been obtained at room temperature for various concentrations in a series of non polar and polar solvents. The concentration effect shows two fluorescence bands, one at shorter wavelength due to monome r and another at longer wavelength due to excimer formation by triplet -triplet annihilation process. The excited state dipole moments of bot h monomer and dimer are calculated by the method of solvatochromism. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and electrochromism.