M. Sambi et al., DETERMINATION OF THE OVERLAYER SUBSTRATE REGISTRY IN NI(1ML)/PT(111) BY ANGLE-SCANNED PHOTOELECTRON DIFFRACTION/, Surface review and letters, 2(6), 1995, pp. 787-793
The site (fcc or hcp) occupied by the atoms of a Ni ML deposited on Pt
(111) is determined in this paper using angle-scanned photoelectron di
ffraction (PD). A full 2 pi MgKalpha-excited Ni-2p(3/2) PD pattern fro
m 1-ML Ni deposited on Pt(111) is compared to single scattering cluste
r-spherical wave (SSC-SW) simulations and the agreement between experi
mental and theoretical data is quantified by R-factor analysis. From t
he present investigation it turns out that Ni atoms occupy hcp sites.
In addition, the Ni-Pt distance has been estimated to be 2.5 +/- 0.1 A
ngstrom.