STUDIES ON COORDINATION BEHAVIOR BETWEEN PRCL3-CENTER-DOT-H2O AND 18C6 IN C2H5OH AND SYNTHESES AND CHARACTERIZATION OF COORDINATION-COMPOUNDS

Authors
XUE GL REN DH HU SM FAN SY YANG YX LI QD
Citation
Gl. Xue et al., STUDIES ON COORDINATION BEHAVIOR BETWEEN PRCL3-CENTER-DOT-H2O AND 18C6 IN C2H5OH AND SYNTHESES AND CHARACTERIZATION OF COORDINATION-COMPOUNDS, Gaodeng xuexiao huaxue xuebao, 16(10), 1995, pp. 1504-1507
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
16
Issue
10
Year of publication
1995
Pages
1504 - 1507
Database
ISI
SICI code
0251-0790(1995)16:10<1504:SOCBBP>2.0.ZU;2-6
Abstract
The solubilities of ternary system, PrCl3 . 3H(2)O-18C6-C2H5OH, at 25 degrees C were investigated by a semimicro method for the study of pha se equilibrium and the refractive indexes of saturated solutions were determined, Three kinds of stoichiometrical coordination compounds can be formed in the system, their chemical compositions are 2PrCl(3) . 1 8C6 . 6H(2)O . C2H5OH, 4PrCl(3) . 3(18C6). 12H(2)O and PrCl3 . 18C6 . 3H(2)O. The three kinds of coordination compounds were prepared on the basis of tile result of phase equilibrium, and characterized by IR sp ectra, conductivity measurements, TG, DTG and DSC.