SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF 5-COORDINATED AND 6-COORDINATED IRON(I) AND IRON(II) COMPLEXES WITH THE SAME (ETA(5)-C(5)ME(5))FE(DPPE) FRAMEWORK

Authors
HAMON P TOUPET L HAMON JR LAPINTE C
Citation
P. Hamon et al., SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF 5-COORDINATED AND 6-COORDINATED IRON(I) AND IRON(II) COMPLEXES WITH THE SAME (ETA(5)-C(5)ME(5))FE(DPPE) FRAMEWORK, Organometallics, 15(1), 1996, pp. 10-12
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
1
Year of publication
1996
Pages
10 - 12
Database
ISI
SICI code
0276-7333(1996)15:1<10:SAXCO5>2.0.ZU;2-W
Abstract
The one electron reduction of CpFe(dppe)(OSO2CF3) (2) with cobaltocen e gave the d(7) iron(I) CpFe(dppe) (3, 90%) as thermally stable orang e crystals, whereas the one-electron oxidation of 3 with ferrocenium h exafluorophosphate afforded the new d(6) iron(II) 16-electron complex [CpFe(dppe)][PF6] (4, 98%) isolated as an stable orange powder. The X -ray crystal structures of 3 and 4 show that their major structural di fference concerns the ''pyramidalization'' of the metal center.