A NEW APPROACH TO INFRARED SPECTROELECTROCHEMISTRY USING A FIBEROPTICPROBE - APPLICATION TO ORGANOMETALLIC REDOX CHEMISTRY

Authors
SHAW MJ GEIGER WE
Citation
Mj. Shaw et We. Geiger, A NEW APPROACH TO INFRARED SPECTROELECTROCHEMISTRY USING A FIBEROPTICPROBE - APPLICATION TO ORGANOMETALLIC REDOX CHEMISTRY, Organometallics, 15(1), 1996, pp. 13-15
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
1
Year of publication
1996
Pages
13 - 15
Database
ISI
SICI code
0276-7333(1996)15:1<13:ANATIS>2.0.ZU;2-S
Abstract
A mid-IR fiber-optic cable operating as a ''dip'' probe has been used to obtain IR spectra of electrolysis solutions. The probe is employed in conventional electrochemical cells to sample the bulk of solution b efore, during, and after electrolysis. Unlike other spectroelectrochem ical methods, this technique requires no cell design compromises which diminish the accuracy of the electrochemical data.