CYCLOADDITION OF PHOSPHAALKYNES TO HIGH-OXIDATION-STATE METAL ALKYLIDENES - SYNTHESIS AND CHARACTERIZATION OF A UNIQUE PHOSPHAMETALLACYCLOBUTENE VIA AN ALKOXIDE LIGAND SHIFT

Authors
JAMISON GM SAUNDERS RS WHEELER DR MCCLAIN MD LOY DA ZILLER JW
Citation
Gm. Jamison et al., CYCLOADDITION OF PHOSPHAALKYNES TO HIGH-OXIDATION-STATE METAL ALKYLIDENES - SYNTHESIS AND CHARACTERIZATION OF A UNIQUE PHOSPHAMETALLACYCLOBUTENE VIA AN ALKOXIDE LIGAND SHIFT, Organometallics, 15(1), 1996, pp. 16-18
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
1
Year of publication
1996
Pages
16 - 18
Database
ISI
SICI code
0276-7333(1996)15:1<16:COPTHM>2.0.ZU;2-O
Abstract
The phosphametallacycle 3, [ArN][RO]Mo=C-(t-Bu)P(OR)C(H)(t-Bu) (Ar = 2 ,6-(i-Pr)(2)-C6H3, R = CMe-(CF3)(2)), is formed from the cycloaddition of tert-butylphosphaacetylene to the high-oxidation-state molybdenum alkylidene [ArN][RO]Mo-2=C(H)(t-Bu), accompanied by an alkoxide metal- to-ligand shift. The 1-phospha-3-molybdacyclobut-2-ene has been charac terized by multinuclear NMR spectroscopy and its molecular structure d etermined by X-ray crystallographic analysis.