STRUCTURAL DIVERSITY IN LANTHANIDE PHOSPHIDO COMPLEXES - FORMATION AND X-RAY CRYSTAL-STRUCTURE DETERMINATION OF AN UNUSUAL DINUCLEAR PHOSPHIDO COMPLEX OF DIVALENT SAMARIUM - )P]SM[MU-P(SIME(3))(2)]SM-3(THF)(3)CENTER-DOT-C7H8

Authors
RABE GW RIEDE J SCHIER A
Citation
Gw. Rabe et al., STRUCTURAL DIVERSITY IN LANTHANIDE PHOSPHIDO COMPLEXES - FORMATION AND X-RAY CRYSTAL-STRUCTURE DETERMINATION OF AN UNUSUAL DINUCLEAR PHOSPHIDO COMPLEX OF DIVALENT SAMARIUM - )P]SM[MU-P(SIME(3))(2)]SM-3(THF)(3)CENTER-DOT-C7H8, Organometallics, 15(1), 1996, pp. 439-441
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
1
Year of publication
1996
Pages
439 - 441
Database
ISI
SICI code
0276-7333(1996)15:1<439:SDILPC>2.0.ZU;2-#
Abstract
The dinuclear phosphido complex of divalent samarium [(Me(3)Si)(2)P]Sm [mu-P(SiMe(3))(2)]Sm-3(thf)(3) (1) can be readily made from SmI2(thf)( 2) and 2 equiv of KP-(SiMe(3))(2) in tetrahydrofuran solution. The unu sual molecular structure of complex 1 in the solid state is discussed.