SYNTHESIS OF A ZWITTERIONIC P-COORDINATED COMPLEX WITH BIS(DIPHENYLPHOSPHINO)ACETYLENE

Authors
LOUATTANI E SUADES J URTIAGA K ARRIORTUA MI SOLANS X
Citation
E. Louattani et al., SYNTHESIS OF A ZWITTERIONIC P-COORDINATED COMPLEX WITH BIS(DIPHENYLPHOSPHINO)ACETYLENE, Organometallics, 15(1), 1996, pp. 468-471
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
1
Year of publication
1996
Pages
468 - 471
Database
ISI
SICI code
0276-7333(1996)15:1<468:SOAZPC>2.0.ZU;2-Z
Abstract
New cationic, [(Fp)Ph(2)PC=CPPh(2)(F-p)](2+) (1) and [(Fp)Ph(2)PC=CPPh (2)](+) (2), and anionic, [Fe-3(CO)(9)(mu 3-CCH3)(Ph(2)PC= CPPh(2))](- ) (3) and [{Fe-3(CO)9(mu(3)-CCH3)}2(Ph(2)PC=CPPh(2))](2-) (4), P-coord inate complexes with bis(diphenylphosphino)acetylene have been prepare d. The zwitterionic P-coordinated iron complex [{Fe-3(CO)(9)(mu 3-CCH3 )}Ph(2)PC=CPPh(2)(Fp)] (5) has been synthesized in two different ways and characterized by X-ray crystallography.