We report growth and characterization details of lattice matched and c
oherently strained InxGa1-xAs/InP quantum well structures grown on mis
oriented [111]B InP substrates. Photoluminescence from a range of such
structures, grown on substrates with optimum misorientation, show lin
ewidths as good or better than equivalent [100] layers. Multiquantum w
ell (MQW) samples with relatively modest compressive strain show X-ray
diffraction data characteristic of highly uniform pseudomorphic quant
um wells. With increased strain (x = 0.63), relaxation is evident thro
ugh a degradation of the diff acted peak widths and through the observ
ation of defects in the surface morphology. Fabricated strained p-i(MQ
W)-n diode structures exhibit low reverse leakage current densities (e
.g. j = 6 mu A/ cm(2)). Room temperature photocurrent measurements on
these devices show a strong excitonic blue shift (15 nm) with applied
bias, as a consequence of the built-in piezoelectric field. The rate o
f peak shift, up to 8 nm/V, demonstrates excellent potential for low v
oltage optical modulator applications at around 1.55 mu m wavelength.