Jc. Farmer et al., CAPACITIVE DEIONIZATION OF NACL AND NANO3 SOLUTIONS WITH CARBON AEROGEL ELECTRODES, Journal of the Electrochemical Society, 143(1), 1996, pp. 159-169
A process for the capacitive deionization of water with a stack of car
bon aerogel electrodes has been developed by Lawrence Livermore Nation
al Laboratory. Unlike ion exchange, one of the more conventional deion
ization processes, no chemicals are required for regeneration of the s
ystem. Electricity is used instead. Water with various anions and cati
ons is pumped through the electrochemical cell. After polarization, io
ns are electrostatically removed from the water and held in the electr
ic double layers formed at the surfaces of electrodes. The water leavi
ng the cell is purified, as desired. The effects of cell voltage and c
ycling on the electrosorption capacities for NaCl and NaNO3 have been
investigated and are reported here.