NOVEL ZIRCONIUM COMPLEXES DERIVED FROM C-2-SYMMETRICAL DIAMIDE LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF C6H3)(2)-2,2'-(NCH(2)C(6)H(4)PH-4)(2)-6,6'-ME(2))]

Authors
CLOKE FGN GELDBACH TJ HITCHCOCK PB LOVE JB
Citation
Fgn. Cloke et al., NOVEL ZIRCONIUM COMPLEXES DERIVED FROM C-2-SYMMETRICAL DIAMIDE LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF C6H3)(2)-2,2'-(NCH(2)C(6)H(4)PH-4)(2)-6,6'-ME(2))], Journal of organometallic chemistry, 506(1-2), 1996, pp. 343-345
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
506
Issue
1-2
Year of publication
1996
Pages
343 - 345
Database
ISI
SICI code
0022-328X(1996)506:1-2<343:NZCDFC>2.0.ZU;2-9
Abstract
The novel alkene polymerisation cocatalysts [Zr(CH(2)Ph)(2)(ArDABP)] c ontaining the biphenyl-bridged ligands 2,2'-di-(N-benzyl)amino-6,6'-di methylbiphenyl (ArDABP, Ar = CH(2)C(6)H(4)(t)Bu-4 or CH2C6H4-Ph) displ ay averaged C-2-symmetry in solution and an eta(2)-benzyl coordination mode in the solid state.