COMPUTER-SIMULATION OF ADSORPTION FROM BINARY AR-KR SOLUTIONS IN THINSLIT PORES OF GRAPHITE

Authors
PIOTROVSKAYA EM BRODSKAYA EN
Citation
Em. Piotrovskaya et En. Brodskaya, COMPUTER-SIMULATION OF ADSORPTION FROM BINARY AR-KR SOLUTIONS IN THINSLIT PORES OF GRAPHITE, Langmuir, 9(12), 1993, pp. 3548-3552
Citations number
20
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
9
Issue
12
Year of publication
1993
Pages
3548 - 3552
Database
ISI
SICI code
0743-7463(1993)9:12<3548:COAFBA>2.0.ZU;2-X
Abstract
Grand canonical ensemble Monte Carlo calculations were held for Ar-Kr binary solution in slit graphite pores of different width at 88 K. The main aim of the present work was to investigate the dependence of the adsorption properties for binary films on the pore width. It was show n that the graphite pore sizes influence significantly the selective a dsorption of krypton only in the range of pore widths less than six mo lecular diameters. For very thin pores the sizes of MC cells in x and y directions are quite important for adsorption characteristics.