MICROSTRUCTURE AND TEXTURE OF PITCH-BASED RIBBON FIBERS FOR THERMAL MANAGEMENT

Citation
Ke. Robinson et Dd. Edie, MICROSTRUCTURE AND TEXTURE OF PITCH-BASED RIBBON FIBERS FOR THERMAL MANAGEMENT, Carbon, 34(1), 1996, pp. 13-36
Citations number
43
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
CarbonACNP
ISSN journal
00086223
Volume
34
Issue
1
Year of publication
1996
Pages
13 - 36
Database
ISI
SICI code
0008-6223(1996)34:1<13:MATOPR>2.0.ZU;2-0
Abstract
The textures and microstructures of three different experimental mesop hase pitch-based ribbon fibers were studied using the complementary te chniques of scanning and transmission electron microscopy and wide ang le X-ray diffraction. The effect of mesophase pitch precursor and capi llary entry design on the structure and heat transfer capabilities of these ribbon-shaped fibers was investigated. It was found that ribbon fibers melt-spun from a synthetic, naphthalene-based mesophase had hig her degrees of preferred orientation and graphitization, larger crysta llite sizes and lower electrical resistivities than those of fibers me lt-spun from a petroleum-based, heat-soaked mesophase. However, capill ary entry design proved to be critical to the development of a more li near transverse texture and a structure that one might expect to be mo re conducive to axial heat transfer.