BUBBLE POINT PRESSURES AND DENSITIES FOR THE BINARY-SYSTEMS OF PROPANE WITH TRIACONTANE, HEXATRIACONTANE, TETRACONTANE, PENTACONTANE, AND SQUALANE AT 353-373 K AND 4.00-7.00 MPA

Citation
M. Aalto et S. Liukkonen, BUBBLE POINT PRESSURES AND DENSITIES FOR THE BINARY-SYSTEMS OF PROPANE WITH TRIACONTANE, HEXATRIACONTANE, TETRACONTANE, PENTACONTANE, AND SQUALANE AT 353-373 K AND 4.00-7.00 MPA, Journal of chemical and engineering data, 41(1), 1996, pp. 79-83
Citations number
11
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
41
Issue
1
Year of publication
1996
Pages
79 - 83
Database
ISI
SICI code
0021-9568(1996)41:1<79:BPPADF>2.0.ZU;2-E
Abstract
Bubble point pressures and densities were measured with a variable vol ume cell for the binary systems propane + triacontane (n-C30H62), + he xatriacontane (n-C36H74), + tetracontane (n-C40H82), + pentacontane (n -C50H102), and + squalane (C30H62,2,6,10,15,19,23-hexamethyltetracosan e). The densities were measured for compressed liquids or supercritica l fluids in the one-phase region. The studied temperature and pressure ranges were 353-373 K and 4.00-7.00 MPa, respectively. The mass fract ions of the long-chain alkanes varied between 0 and 0.0326. It was fou nd that the densities of the mixtures increased almost linearly with t he mass fractions of the heavy alkanes. The effects of all the long-ch ain alkanes on the density did not depend on molar mass. Bubble point pressures decreased only very slightly as the mass fractions of the lo ng-chain alkanes increased.