T. Ohji et al., PARTICLE MATRIX INTERFACE AND ITS ROLE IN CREEP INHIBITION IN ALUMINA/SILICON CARBIDE NANOCOMPOSITES/, Journal of the American Ceramic Society, 79(1), 1996, pp. 33-45
This study focuses on interfacial bonding between intergranular silico
n carbide particles and an alumina matrix, to determine the creep inhi
bition mechanism of alumina/silicon carbide nanocomposites, It is reve
aled that the silicon carbide/alumina interface possesses much stronge
r bonding than the alumina/alumina interface through three approaches:
investigation of fracture toughness and fracture mode acid considerat
ion of internal thermal stresses acting at grain boundaries, estimatio
n of equilibrium thickness of intergranular glassy films by force bala
nce, and direct observation of grain boundaries by TEM. The rigid bond
ing of alumina/silicon carbide interfaces causes inhibition of vacancy
nucleation and annihilation at the interfaces, causing remarkably imp
roved creep resistance of the nanocomposite.