ENZYMATIC VERSUS CHEMICAL CARBON-DIOXIDE UTILIZATION .1. THE ROLE OF METAL CENTERS IN CARBOXYLATION REACTIONS

Authors
ARESTA M QUARANTA E TOMMASI I GIANNOCCARO P CICCARESE A
Citation
M. Aresta et al., ENZYMATIC VERSUS CHEMICAL CARBON-DIOXIDE UTILIZATION .1. THE ROLE OF METAL CENTERS IN CARBOXYLATION REACTIONS, Gazzetta chimica italiana, 125(11), 1995, pp. 509-538
Citations number
244
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
125
Issue
11
Year of publication
1995
Pages
509 - 538
Database
ISI
SICI code
0016-5603(1995)125:11<509:EVCCU.>2.0.ZU;2-7
Abstract
A comparative review of the role of metal centres utilizing carbon dio xide in biological and chemical carboxylation reactions is reported. T he interaction of the cumulene with metal centres is also discussed an d the mode of bonding is related to the reactivity.