EVIDENCE FOR THE REMOVAL OF GASEOUS HNO3 INSIDE THE ARCTIC POLAR VORTEX IN JANUARY 1992

Citation
M. Hopfner et al., EVIDENCE FOR THE REMOVAL OF GASEOUS HNO3 INSIDE THE ARCTIC POLAR VORTEX IN JANUARY 1992, Geophysical research letters, 23(2), 1996, pp. 149-152
Citations number
23
Categorie Soggetti
Geosciences, Interdisciplinary
ISSN journal
00948276
Volume
23
Issue
2
Year of publication
1996
Pages
149 - 152
Database
ISI
SICI code
0094-8276(1996)23:2<149:EFTROG>2.0.ZU;2-W
Abstract
Unexpectedly low column amounts of HNO3 (1.3x10(16) cm(-2)) inside the Arctic polar vortex were obtained on January 9, 1992 by airborne FTIR emission measurements. After correction for dynamic variations it is concluded that about 40% of the column HNO3 had been removed from the gas phase. The observed depletion is consistent with a nearly equilibr ium saturation of HNO3 over nitric acid trihydrate. It cannot be expla ined by the uptake of HNO3 in ternary H2SO4/H2O/HNO3 mixtures.