HIGH-PRESSURE MEDIATED ASYMMETRIC DIELS-ALDER REACTION OF CHIRAL SULFINYLACRYLATE DERIVATIVES WITH FURAN AND 2-METHOXYFURAN

Authors
YAMAKOSHI YN GE WY SUGITA J OKAYAMA K TAKAHASHI T KOIZUMI T
Citation
Yn. Yamakoshi et al., HIGH-PRESSURE MEDIATED ASYMMETRIC DIELS-ALDER REACTION OF CHIRAL SULFINYLACRYLATE DERIVATIVES WITH FURAN AND 2-METHOXYFURAN, Heterocycles, 42(1), 1996, pp. 129-133
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
42
Issue
1
Year of publication
1996
Pages
129 - 133
Database
ISI
SICI code
0385-5414(1996)42:1<129:HMADRO>2.0.ZU;2-N
Abstract
Asymmetric Diels-Alder reaction of chiral sulfinylacrylate derivatives (1 and 2) with furan (3) and 2-methoxyfuran (4) proceeded under high pressure (1.2 GPa) conditions to give endo cycloadducts(6c-f). The abs olute configuration of adduct (6) was confirmed by conversion of 6e to (-)-COTC (9).