REACTIONS OF SMALL CARBON ANIONS WITH HYDROGEN-SULFIDE

Authors
HOPWOOD FG FISHER KJ WILLETT GD GREENHILL PG
Citation
Fg. Hopwood et al., REACTIONS OF SMALL CARBON ANIONS WITH HYDROGEN-SULFIDE, Rapid communications in mass spectrometry, 10(1), 1996, pp. 110-113
Citations number
45
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
Journal title
Rapid communications in mass spectrometry → ACNP
ISSN journal
09514198
Volume
10
Issue
1
Year of publication
1996
Pages
110 - 113
Database
ISI
SICI code
0951-4198(1996)10:1<110:ROSCAW>2.0.ZU;2-K
Abstract
A Fourier transform mass spectrometry analysis of the ion/molecule rea ctions of small carbon cluster anions (C-n(-), n=4-9) with hydrogen su lfide are reported, Carbon anions were produced from a partially graph itized petroleum coke. All the anions proved to be reactive towards H2 S, different reaction products being produced from the even- and odd-n umbered carbon anions. Second-order rate constants were determined for the reactions.