SURFACE-ENHANCED RESONANCE RAMAN-SPECTROSCOPY OF 2-PYRIDYLHYDRAZONE AND 1,10-PHENANTHROLINE CHELATE COMPLEXES WITH METAL-IONS ON COLLOIDAL SILVER

Authors
HIDALGO M MONTES R LASERNA JJ RUPEREZ A
Citation
M. Hidalgo et al., SURFACE-ENHANCED RESONANCE RAMAN-SPECTROSCOPY OF 2-PYRIDYLHYDRAZONE AND 1,10-PHENANTHROLINE CHELATE COMPLEXES WITH METAL-IONS ON COLLOIDAL SILVER, Analytica chimica acta, 318(2), 1996, pp. 229-237
Citations number
39
Categorie Soggetti
Chemistry Analytical
Journal title
Analytica chimica acta → ACNP
ISSN journal
00032670
Volume
318
Issue
2
Year of publication
1996
Pages
229 - 237
Database
ISI
SICI code
0003-2670(1996)318:2<229:SRRO2A>2.0.ZU;2-F
Abstract
Surface-enhanced resonance Raman spectra (SERRS) of the complexes PAPH -Co(II), PAPH-Ni(II), PAPH-Fe(II), and PHEN-Fe(II) (PAPH = 2-pyridine carboxyaldehyde 2-pyridylhydrazone and PHEN = 1,10-phenanthroline) ads orbed on silver colloid have been studied. Differences among SERS spec tra of ligands and SERRS spectra of complexes have been investigated. Ultra-sensitive methods for metal determination with limits of detecti on at the ng ml(-1) level are presented.