The basic principles and major applications of on-site/in situ environ
mental and process analysis by mass spectrometry are presented. This p
aper mainly deals with instrumental procedures, especially sample intr
oduction methods, such as direct methods, atmospheric pressure samplin
g, membrane inlet mass spectrometry, liquid injection systems and gas
chromatographic methods, together with the properties of various analy
ser types and data handling requirements. In addition, the development
of portable mass spectrometers is discussed. The on-site/in situ appl
ications of mass spectrometry are summarized and a few applications ar
e discussed in some detail.