DONORSTABILIZED ALUMINIUM(I) IODIDE

Authors
ECKER A SCHNOCKEL H
Citation
A. Ecker et H. Schnockel, DONORSTABILIZED ALUMINIUM(I) IODIDE, Zeitschrift fur anorganische und allgemeine Chemie, 622(1), 1996, pp. 149-152
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
1
Year of publication
1996
Pages
149 - 152
Database
ISI
SICI code
0044-2313(1996)622:1<149:DAI>2.0.ZU;2-T
Abstract
A metastable solution of Al-1-iodide is formed by quenching of gaseous Al-1-iodide, formed from Al-(l) and HI(g) at about 1000 degrees C wit h a mixture of toluene/diethylether. Using triethylamine as donor and solvent crystalline (AII . NEt(3))(4) 1 can be isolated: a planar Al-4 ring with an Al-Al distance of 265 pm is the most important structura l feature in this first roomtemperature stable Al-1-Iodide.