St. Hussain, THE EFFECT OF ALLOYING ON SELECTIVITY AND ACTIVITY FOR CARBON-MONOXIDE HYDROGENATION OVER RU-MN SIO2 SUPPORTED SYSTEM/, Journal of the Chemical Society of Pakistan, 17(3), 1995, pp. 133-137
The Ru:Mn/SiO2 supported system with various level of Mn war prepared
by co-impregnation method dispersed on high surface area SiO2 support.
The system war investigated for CO hydrogenation reaction. The cataly
tic activity and product selectivities data reveals electronic and ens
emble street produced by the addition of Mn to Ru/SiO2 system It is su
ggested that addition cf Mn produces new surface sites Ru:Mn bimetalli
cs which modify the catalytic behaviour electronically and geometrical
ly.