Rs. Stein et al., OPTICAL-PROPERTIES OF POLYMERS AND LIQUID-CRYSTALS IN ELECTRICAL, MAGNETIC, AND HYDRODYNAMIC FIELDS, Pure and applied chemistry, 67(12), 1995, pp. 1971-1982
The behavior of polymer molecules oriented by mechanical, electrical,
and magnetic fields is discussed. The consequences of such orientation
on optical properties such as birefringence, dichroism, and scatterin
g is analyzed, and means for studying these are illustrated. Particula
r cases which are described are (a) the change in birefringence dichro
ism, and light scattering when a crystalline polymer is subject to str
ain, (b) the change in small-angle neutron scattering when a polymer m
elt or crosslinked rubber is deformed, (c) the change in birefringence
and light scattering accompanying the stress-induced crystallization
of a polymer, and (d) the change in light scattering accompanying the
shearing of a thermotropic liquid crystal polymer.