SUB-GLASS TRANSITION MOTIONS IN LINEAR AND CROSS-LINKED BISPHENOL-TYPE EPOXY-RESINS BY DEUTERIUM LINE-SHAPE NMR

Deuterium solid-state echo delay line shapes are used to establish the local motions occurring in linear and cross-linked epoxy systems base d on Bisphenol A. Four isotopically labeled samples were prepared: lin ear and cross-linked resins with deuterated methylene units, and linea r and cross-linked resins with deuterated phenylene units. Two local m otions are observed in all four samples: trans-gauche isomerization of the methylene units and pi flips of the phenylene units. The solid-st ate echo delay line shapes were simulated to obtain the rates of motio n, the amplitudes of motion, and apparent distribution of rates, and t he apparent temperature dependence of the rates. The two jump motions differ by about an order of magnitude in rate, with the JE flip proces s being the faster of the two. Both have similar distributions of rela xation times given by a stretched exponential correlation function wit h an exponent of 0.6-0.7. The apparent activation energy for the pi fl ip process is 50 kJ/mol and for the trans-gauche isomerization, 57 kJ/ mol. For a given frequency, the breadth and temperature of the shear l oss peak can be calculated from the information determined from the NM R data. Both motional processes lie in the envelope of relaxation refe rred to as the beta process, with the pi flips occurring on the lower temperature side of the envelope and the trans-gauche isomerization oc curring on the higher temperature side. These two motions do not appea r to account for all of the relaxations contributing to the beta peak.