MOLECULAR-STRUCTURE OF (DIETHYLDITHIOCARBOMOYL)DIPHENYLTHIOPHOSPHINATE

Citation
Va. Alfonsov et al., MOLECULAR-STRUCTURE OF (DIETHYLDITHIOCARBOMOYL)DIPHENYLTHIOPHOSPHINATE, Russian chemical bulletin, 44(10), 1995, pp. 1897-1899
Citations number
4
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
44
Issue
10
Year of publication
1995
Pages
1897 - 1899
Database
ISI
SICI code
1066-5285(1995)44:10<1897:MO(>2.0.ZU;2-J
Abstract
X-Ray study of (diethyldithiocarbomoyl)diphenylthiophosphinate was car ried out. A Z-conformation of the diethyldithiocarbomoyl ligand, which results in a short nonvalent intramolecular P...S contact (3.315 Angs trom), is realized in the molecule. Steric hindrances in the molecule increase the P-S-C bond angle to 106.39 degrees.