X-Ray study of (diethyldithiocarbomoyl)diphenylthiophosphinate was car
ried out. A Z-conformation of the diethyldithiocarbomoyl ligand, which
results in a short nonvalent intramolecular P...S contact (3.315 Angs
trom), is realized in the molecule. Steric hindrances in the molecule
increase the P-S-C bond angle to 106.39 degrees.