THE FIRST EXAMPLES OF METALLATRICARBOLLIDES - ISOMERIC 12-VERTEX CYCLOPENTADIENYL FERRATRICARBADODECABORANES [(ETA(5)-C5H5)-CLOSO-FEC3B8H11]

Authors
STIBR B HOLUB J TEIXIDOR F VINAS C
Citation
B. Stibr et al., THE FIRST EXAMPLES OF METALLATRICARBOLLIDES - ISOMERIC 12-VERTEX CYCLOPENTADIENYL FERRATRICARBADODECABORANES [(ETA(5)-C5H5)-CLOSO-FEC3B8H11], Collection of Czechoslovak Chemical Communications, 60(12), 1995, pp. 2023-2027
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
60
Issue
12
Year of publication
1995
Pages
2023 - 2027
Database
ISI
SICI code
0010-0765(1995)60:12<2023:TFEOM->2.0.ZU;2-K
Abstract
The first metallatricarbollides, six isomeric twelve-vertex metallatri carbaboranes of general structure [(eta(5)-C5H5)-closo-FeC3B8H11], are formed in the reaction between TI[nido-7,8,9-C3B8H11] and [(eta(5)-C5 H5)-Fe(CO)(2)I] in toluene at reflux. Two of them have so far been sat isfactorily identified as [3-(eta(5)-C5H5)closo-3,1,2,4-FeC3B8H11] and [2-(eta(5)-C5H5)-Closo-2,1,8,11-FeC3B8H11] by NMR spectroscopy.