ASSIGNMENT OF NITROGEN STEREOCHEMISTRY OF AGROCLAVINE AND ELYMOCLAVINE 6-N-OXIDES

Authors
KREN V NEMECEK J PRIKRYLOVA V
Citation
V. Kren et al., ASSIGNMENT OF NITROGEN STEREOCHEMISTRY OF AGROCLAVINE AND ELYMOCLAVINE 6-N-OXIDES, Collection of Czechoslovak Chemical Communications, 60(12), 1995, pp. 2165-2169
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
60
Issue
12
Year of publication
1995
Pages
2165 - 2169
Database
ISI
SICI code
0010-0765(1995)60:12<2165:AONSOA>2.0.ZU;2-F
Abstract
Both possible 6-N-oxides of agroclavine (I) and elymoclavine (II) were prepared by hydrogen peroxide oxidation. Their H-1 and C-13 NMR spect ra were assigned and the conformation of the D ring (half-chair) was d etermined. Absolute configuration at 6-N was established by NMR and mo lecular modelling.