A SESQUITERPENE ALCOHOL FROM STREPTOMYCES-CITREUS CBS-109.60

Authors
GANSSER D POLLAK FC BERGER RG
Citation
D. Gansser et al., A SESQUITERPENE ALCOHOL FROM STREPTOMYCES-CITREUS CBS-109.60, Journal of natural products, 58(11), 1995, pp. 1790-1793
Citations number
16
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy
Journal title
Journal of natural products → ACNP
ISSN journal
01633864
Volume
58
Issue
11
Year of publication
1995
Pages
1790 - 1793
Database
ISI
SICI code
0163-3864(1995)58:11<1790:ASAFSC>2.0.ZU;2-A
Abstract
Separation of an extract of Streptomyces citreus CBS 109.60 by column chromatography and preparative gas chromatography yielded the novel se squiterpene alcohol 1, whose structure and relative conformation were established by spectroscopic means. Comparison of the its spectral dat a with compounds of known absolute configuration led to assignment of the stereochemistry at C-4 and C-7. Thus, 1 was assigned as 4S, 7R-ger macra-1 (1O)E, 5E-diene-11-ol.