MONOMERIC TRILITHIUM-TRIS[TERT-BUTYLDIMET HYLSILYLAMIDO]PHENYLSILANE,PHSI[NLI(THF)SIME(2)CME(3)](3) - SYNTHESIS AND CRYSTAL-STRUCTURE

Authors
HEMME I KLINGEBIEL U FREITAG S STALKE D
Citation
I. Hemme et al., MONOMERIC TRILITHIUM-TRIS[TERT-BUTYLDIMET HYLSILYLAMIDO]PHENYLSILANE,PHSI[NLI(THF)SIME(2)CME(3)](3) - SYNTHESIS AND CRYSTAL-STRUCTURE, Zeitschrift fur anorganische und allgemeine Chemie, 621(12), 1995, pp. 2093-2096
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
12
Year of publication
1995
Pages
2093 - 2096
Database
ISI
SICI code
0044-2313(1995)621:12<2093:MTH>2.0.ZU;2-6
Abstract
Lithiated tert-butyldimethylsilylamine reacts with trifluorophenylsila ne in a molar ratio 2:1 or 3:1 to give the bis- and tris(silylamino)si lanes 1 [(Me(3)CSiMe(2)NH)(2)SiFPh] and 2 [(Me(3)CSiMe(2)NH)(3)SiPh]. The trilithium derivative 3 [Me(3)CSiMe(2)NLi(thf)](3)SiPh is obtained in the reaction of 2 with n-BuLi in hexane/thf. 3 crystallizes as a m onomer forming three planar four-membered (LiNSiN)-rings. The results of the crystal structure of 3 are discussed.