LOW-TEMPERATURE STATES IN THE BETA-CEH2+X PHASE

Citation
Ig. Ratishvili et al., LOW-TEMPERATURE STATES IN THE BETA-CEH2+X PHASE, Journal of alloys and compounds, 231(1-2), 1995, pp. 115-120
Citations number
8
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
ISSN journal
09258388
Volume
231
Issue
1-2
Year of publication
1995
Pages
115 - 120
Database
ISI
SICI code
0925-8388(1995)231:1-2<115:LSITBP>2.0.ZU;2-7
Abstract
The low temperature ordering processes in the single-phase system beta -CeH2-x are analysed using the mean-field approximation of the static concentration wave theory. It is applied to the subsystem of the x hyd rogen atoms located in the octahedral interstices;of the f.c.c. metal lattice. It is shown that, depending upon the value of x, these hydrog en atoms form, in the low temperature, limit two different ordered sta tes, in agreement with the neutron diffraction data. In addition, the boundary values x(1) and x(2) (where both ordered states are equally f avourable) coincide closely with the concentrations of the low tempera ture ''pseudocubic'' phases observed in the X-ray experiments.