Muon spin rotation (mu SR) experiments on single-crystal samples of Sc
Hx, with x = 0, 0.05, 0.10 and 0.25, were performed in order to invest
igate the muon location and possible systematic variations in muon dyn
amics in these systems. The angular and magnetic field dependence of t
he mu SR relaxation rates shows that at temperatures below 50 K the mu
on is localized at the interstitial tetrahedral (T) sites. The results
for pure Sc, covering a wide range of high and low fields, are cohere
nt with the picture that the muon performs fast tunnelling between two
adjacent T sites, separated by 2z = 0.18c, above and below the a-b pl
ane. This value for the muon position along the c axis is remarkably n
ear the 2z = 0.194c found for D in Sc by neutron diffraction. The anis
otropy of the relaxation rate at low magnetic fields varies sensitivel
y with the H concentration, indicating a change in the ratio of the ra
dial, muon-induced and the partly inherent, uniaxial electric field gr
adients at the position of the Sc nuclei.