Y. Nakamura et al., CHARACTERISTICS OF A HYDROGEN-ABSORBING ALLOY DEVELOPED FOR A PORTABLE FUEL-CELL, Journal of alloys and compounds, 231(1-2), 1995, pp. 898-902
We have been developing a 250 W class portable fuel cell system with a
hydrogen supplier utilizing a hydrogen-absorbing alloy to meet demand
for a clean and silent power source. A Mm-Y-Ni-Mn alloy with the CaCu
5 structure was developed for the hydrogen supplier and characterized
with regard to the amount of the effective hydrogen, X(eff) under oper
ating conditions of the fuel cell. X(eff) values between two arbitrary
temperature and pressure conditions were evaluated from parameters of
a P-C isotherms model. The operating performance of the fuel cell uni
t was examined and the hydrogen supplier using this alloy was characte
rized. The hydrogen supplier and the fuel cell unit showed a successfu
l operating performance, The calculated X(eff) value under the operati
ng conditions of the fuel cell well agreed with its actual operation r
esult. It is concluded that the method of evaluating X(eff) by using t
he P-C isotherms model could contribute to designing the fuel cell sys
tem.