This paper reports the results of molecular dynamics (MD) simulations
of isomerization and evaporation processes of the aniline-Ar-2 cluster
. The trajectory results are analyzed in terms of a simple unimolecula
r kinetics scheme in order to extract isomer-specific evaporation rate
constants. The less stable isomer, denoted (2/0) is found to have an
evaporation rate constant that is about 25% smaller than that for the
more stable isomer, (1/1). This result is explained in terms of the de
nsities of states associated with each isomer. We present preliminary
results on the aniline-Ar-3 cluster and connect this latter system to
possible experiments. (C) 1996 American Institute of Physics.