FACILE OXIDATIVE DECARBOXYLATION OF ARYLACETIC ACIDS AND OXIDATION OFALPHA-BROMOALKYL KETONE BY SODIUM METAPERIODATE IN THE PRESENCE OF DIBENZO-(18)-CROWN-6 AND PTC

Authors
KORE AR SALUNKHE MM
Citation
Ar. Kore et Mm. Salunkhe, FACILE OXIDATIVE DECARBOXYLATION OF ARYLACETIC ACIDS AND OXIDATION OFALPHA-BROMOALKYL KETONE BY SODIUM METAPERIODATE IN THE PRESENCE OF DIBENZO-(18)-CROWN-6 AND PTC, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 35(2), 1996, pp. 151-153
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
35
Issue
2
Year of publication
1996
Pages
151 - 153
Database
ISI
SICI code
0376-4699(1996)35:2<151:FODOAA>2.0.ZU;2-A
Abstract
Arylacetic acids and alpha-bromoalkyl ketone have been oxidized into c arbonyl compounds and acids in high yields, respectively with sodium m etaperiodate in refluxing ethanol in the presence of benzyltriethylamm onium chloride and dibenzo-(18)-crown-6. Conducting the reaction witho ut either phase transfer catalyst (PTC) or dibenzo-(18)-crown-6 (DB-18 -C-6) results in lower yields than with both catalysts. It has been de monstrated that the spatial co-ordination of ion and ligand cavity pla ys important role in using crown ethers.