DIHYDROXYLATION GLYCOL CLEAVAGE OF TRICARBONYL(TRIENE)IRON COMPLEXES/

Authors
DONALDSON WA SHANG LW
Citation
Wa. Donaldson et Lw. Shang, DIHYDROXYLATION GLYCOL CLEAVAGE OF TRICARBONYL(TRIENE)IRON COMPLEXES/, Tetrahedron letters, 37(4), 1996, pp. 423-424
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
4
Year of publication
1996
Pages
423 - 424
Database
ISI
SICI code
0040-4039(1996)37:4<423:DGCOTC>2.0.ZU;2-T
Abstract
(Polyene)Fe(CO)(3) complexes (1) are shown to be stable to a two-step osmylation/periodate cleavage sequence to produce (dienal)Fe(CO)(3) co mplexes (2). In contrast, ozonolysis of 1 has been reported to lead to destruction of the complex.