A dynamic mathematical model was developed for the alternating aerobic
-anoxic (AAA) completely mixed activated sludge process for the remova
l of carbonaceous substrate, nitrification, and denitrification. The m
odel is constructed on the Activated Sludge Model No. 1 (ASM 1) of the
International Association on Water Pollution Research Control with so
me revisions including pH and alkalinity. Experimental data obtained f
rom a bench-scale AAA reactor under different operational conditions w
ere used for parameter estimation and model validation. Model paramete
rs were found to agree well with those used by the ASM1. Process perfo
rmance at steady-state and dynamic conditions can be well predicted by
the AAA model. Because nitrite is not treated as a state variable in
the ASM 1, a modified model incorporating nitrite as a state variable
has been developed to account for nitrite accumulation.