W. Pyzuk et al., NOVEL SERIES OF ENAMINOKETONE LIQUID-CRYSTALS HAVING HEXATIC SMECTIC-B PHASE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 237, 1993, pp. 75
Several homologous series of liquid crystals having an aminoketone mes
ogenic core (Liq. Cryst., 10, 593 (1991)), have been synthesized to de
rive some new wide-temperature untilted smectics. Compounds belonging
to three of six novel series have the hexatic smectic B phase between
smectic A and enantiotropic crystal smectic B phases. Eleven of them e
xhibit first order phase transition between smectic B phases, whereas
for other compounds this phase transition is not detectable neither by
DSC nor texture studies. Molecular modifications leading to further u
ntitled hexatic compounds are suggested.