STEREOCHEMICALLY DEFINED CYCLOHEXANEDIOLS THROUGH THE REGIOSELECTIVE RING-OPENING OF SILYLATED EPOXY ALCOHOLS

Authors
ADAM W PREIN M RICHTER MJ
Citation
W. Adam et al., STEREOCHEMICALLY DEFINED CYCLOHEXANEDIOLS THROUGH THE REGIOSELECTIVE RING-OPENING OF SILYLATED EPOXY ALCOHOLS, Tetrahedron, 52(4), 1996, pp. 1231-1234
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
4
Year of publication
1996
Pages
1231 - 1234
Database
ISI
SICI code
0040-4020(1996)52:4<1231:SDCTTR>2.0.ZU;2-J
Abstract
The nucleophilic ring-opening of the silylated epoxy alcohol 2 leads t o highly functionalized building blocks of defined stereochemistry, wh ereby the regioselectivity may be controlled through the proper choice of the nucleophile and the reaction conditions.